Talstar PL Granules can be used for scorpions following the instructions on the product label: To ensure optimum control, treat the building perimeter at dusk to prevent outdoor scorpions from entering the building. Scorpions reside hidden in cracks and voids during the day and are active at night at temperatures above 77ºF/25ºC. Resting areas can be identified at night using a blacklight (UV bulb) as scorpions will fluoresce. These areas should also be treated. Prior to treatment, to increase treatment efficacy, remove trash, debris, or firewood that scorpions may use as resting sites
We also have a great guide here for Scorpion Control with non chemical recommendations.
There are no toxic products labeled for frogs or toads (or reptiles for that matter), and given the highly beneficial nature of these amphibians there is not likely to be anything coming along.The reasons they are on your property are because they can find food and proper habitat, and these are probably your only means for making them go away. Take away their food and they will forage somewhere else. Take away the conditions they need for hiding all day and they will seek refuge someplace else.
Habitat modification may be the more effective way to limit frogs on your property. Frogs are mainly nocturnal, and they seek food at night when it is cooler and damper. During the day they look for cool, damp, dark places to hide. They will hide under dense shrubbery or ground covers, under logs or lumber on the soil, or under large landscape rocks and timbers to avoid the hot, dry sun. Trim shrubbery, remove thick ground-cover, stack lumber or firewood off of the soil a few inches and remove any other objects or debris that come in contact with the soil and can provide harborage. Limit watering to help eliminate moisture from your yard. You can also reduce the amount of insects (the frogs food source) in your yard by treating the grass with a residual insecticide such as Talstar PL.
Talstar PL Granular Insecticide can offer some benefit for ground bees as a prevention.
Ground bees, also known as digger bees, can be very difficult to control no matter what product you use and they most likely will come back to your property year after year unless you do your part to alter your property to make it unfavorable to the bees. Ground bees prefer dry soils with thin grasses so irrigating the area frequently and correcting any issue that causes your grass to be thin will help deter the bees from nesting. In areas where you do not have grass, a layer of mulch will help deter the bees from nesting. Ground bees are solitary bees and are not very aggressive and are known to be a beneficial insect which is why you will not find any products specifically labeled for this type of bee. For current infestations, you would need to use Delta dust in each individual burrow.
Talstar PL Granular Insecticide will kill spiders that contact the treated area. It will not act as a repellent.
Talstar PL Granules are not labeled to control chiggers. Talstar P and Onslaught<span new="" roman;="" font-size:medium"=""> are top-notch professional products and both are labeled for chiggers. Onslaught is micro-encapsulated and will last a little longer on outdoor surfaces which does give it a bit of advantage over Talstar P. Treatments for chiggers should begin in May and could need to continue through the summer as new chiggers move into the area. Treating the entire lawn is of little benefit because chiggers avoid direct sunlight and normally will not infest areas that are mowed or otherwise well maintained. Focus treatment on the unkempt areas of the lawn and lawn edge. You can also use Onslaught to do a barrier treatment around the outside of your home and in your crawl space to stop pests from moving indoors.
Talstar PL Granules are not labeled to control chiggers. Talstar Pand Onslaught are top-notch professional products and both are labeled for chiggers. Onslaught is micro-encapsulated and will last a little longer on outdoor surfaces which does give it a bit of advantage over Talstar P. Treatments for chiggers should begin in May and could need to continue through the summer as new chiggers move into the area. Treating the entire lawn is of little benefit because chiggers avoid direct sunlight and normally will not infest areas that are mowed or otherwise well maintained. Focus treatment on the unkempt areas of the lawn and lawn edge. You can also use Onslaught to do a barrier treatment around the outside of your home and in your crawl space to stop pests from moving indoors.